Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits

被引:137
作者
Chen, HJ
Mao, ZW
Gao, S [1 ]
Chen, XM
机构
[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[2] Jinan Univ, Dept Chem, Guangzhou 510632, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
关键词
D O I
10.1039/b106314f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of the coordination polymer [Mn-3(N-3)(2)(nta)(4)(H2O)(2)] n (nta = nicotinate) consists of trinuclear subunits bridged by mixed mu -1,1-azide and mu -carboxylate-O, O groups, which are linked by mu (3)-nta-N, O, O ligands into a three-dimensional network exhibiting ferrimagnetic-like ordering.
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页码:2320 / 2321
页数:2
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