Belokon's Ni(II) complex as a chiral masked glycine for the diastereoselective synthesis of 2-substituted 1-aminocyclopropane carboxylic acids

被引：30

作者：

Debache, A

Collet, S

Bauchat, P

Danion, D

Euzenat, L

Hercouet, A

Carboni, B

机构：

[1] Univ Rennes 1, Inst Chim, UMR CNRS 6510, F-35042 Rennes, France

[2] Univ Constantine, Inst Chim, Constantine 25000, Algeria

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(01)00106-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(1S,2R)- and (1R,2S)-Allonorcoronamic acids have been efficiently synthesised from the cyclic sulfate of 1,2-propanediol and Belokon's complex (a complex of Ni(II) with glycine-(S)-2-[N '-(N-benzylprolyl)amino]benzophenone Schiff base ligands). The stereochemical outcome of the reaction was totally controlled bq the sulfate partner. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：761 / 764

页数：4

共 26 条

[1]

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