Ionic liquids based on imidazolium and pyrrolidinium salts of the tricyanomethanide anion

被引:89
作者
Forsyth, SA [1 ]
Batten, SR [1 ]
Dai, Q [1 ]
MacFarlane, DR [1 ]
机构
[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia
关键词
D O I
10.1071/CH03245
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel series of tricyanomethanide ionic liquids have been prepared and characterized for potential use as ionic liquid solvents. Full thermal analyses of all salts at ambient and sub-ambient temperatures are reported (melting points-17degrees to 160degreesC). The thermal stability and decomposition temperatures are also presented (T-decomp approximate to 300degreesC). An electrochemical window of similar to3V has been established and the conductivity measured over a range of temperatures (20 mS cm(-1) at 25degreesC).
引用
收藏
页码:121 / 124
页数:4
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