Ionic liquids based on imidazolium and pyrrolidinium salts of the tricyanomethanide anion

被引：89

作者：

Forsyth, SA ^{[1
]}

Batten, SR ^{[1
]}

Dai, Q ^{[1
]}

MacFarlane, DR ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2004年 / 57卷 / 02期

关键词：

D O I：

10.1071/CH03245

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel series of tricyanomethanide ionic liquids have been prepared and characterized for potential use as ionic liquid solvents. Full thermal analyses of all salts at ambient and sub-ambient temperatures are reported (melting points-17degrees to 160degreesC). The thermal stability and decomposition temperatures are also presented (T-decomp approximate to 300degreesC). An electrochemical window of similar to3V has been established and the conductivity measured over a range of temperatures (20 mS cm(-1) at 25degreesC).

引用

页码：121 / 124

页数：4

共 30 条

[11] N-methyl-N-alkylpyrrolidinium hexafluorophosphate salts:: Novel molten salts and plastic crystal phases [J].

Golding, J ;

Hamid, N ;

MacFarlane, DR ;

Forsyth, M ;

Forsyth, C ;

Collins, C ;

Huang, J .

CHEMISTRY OF MATERIALS, 2001, 13 (02) :558-564

[12]

HANTZSCH A, 1899, CHEM BER, V32, P641

[13] The phase behaviour of 1-alkyl-3-methylimidazolium tetrafluoroborates; ionic liquids and ionic liquid crystals [J].

Holbrey, JD ;

Seddon, KR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (13) :2133-2139

[14] Solid state lithium ion conduction in pyrrolidinium imide-lithium imide salt mixtures [J].

Huang, JH ;

Forsyth, M ;

MacFarlane, DR .

SOLID STATE IONICS, 2000, 136 :447-452

[15] Tricyanomethanide and dicyanamide complexes of Cu(II), Ni(II), Co(II), their structures and properties [J].

Kohout, J ;

Jäger, L ;

Hvastijová, M ;

Kozísek, J .

JOURNAL OF COORDINATION CHEMISTRY, 2000, 51 (02) :169-218

[16] CRYSTAL STRUCTURE OF AGC(CN)3 [J].

KONNERT, J ;

BRITTON, D .

INORGANIC CHEMISTRY, 1966, 5 (07) :1193-&

[17] STRUCTURAL, SPECTRAL AND MAGNETIC INVESTIGATIONS OF VARIOUS TYPES OF COMPOUNDS AND THEIR ISOMERS ISOLATED FROM THE SYSTEM COPPER(II)-C(CN)3-PYRAZOLE [J].

KOZISEK, J ;

HVASTIJOVA, M ;

KOHOUT, J ;

MROZINSKI, J ;

KOHLER, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07) :1773-1778

[18] Low viscosity ionic liquids based on organic salts of the dicyanamide anion [J].

MacFarlane, DR ;

Golding, J ;

Forsyth, S ;

Forsyth, M ;

Deacon, GB .

CHEMICAL COMMUNICATIONS, 2001, (16) :1430-1431

[19] Pyrrolidinium imides: A new family of molten salts and conductive plastic crystal phases [J].

MacFarlane, DR ;

Meakin, P ;

Sun, J ;

Amini, N ;

Forsyth, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (20) :4164-4170

[20] Ionic liquids based on imidazolium, ammonium and pyrrolidinium salts of the dicyanamide anion [J].

MacFarlane, DR ;

Forsyth, SA ;

Golding, J ;

Deacon, GB .

GREEN CHEMISTRY, 2002, 4 (05) :444-448

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