Rh(I)-catalyzed allenic Pauson-Khand reaction: first construction of the bicyclo[6.3.0]undecadienone ring system

被引：58

作者：

Mukai, C ^{[1
]}

Hirose, T ^{[1
]}

Teramoto, S ^{[1
]}

Kitagaki, S ^{[1
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Pharmaceut Sci, Kanazawa, Ishikawa 9201192, Japan

来源：

TETRAHEDRON | 2005年 / 61卷 / 46期

关键词：

Pauson-Khand reaction; allenyne; bicyclo[6.3.0]undecadienone; 2,3]-sigmatropic rearrangement; RhCl(CO)(2)](2); RhCl(CO)dppp](2);

D O I：

10.1016/j.tet.2005.08.088

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Rh(I)-catalyzed Pauson-Khand reaction of allenynes afforded the bicyclo[6.3.0]undecadienones as well as their benzo and furo derivatives. In addition, a novel [RhCl(CO)(2)](2)-catalyzed [2,3]-sigmatropic rearrangement of the sulfinic ester species of propargyl alcohols was developed. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：10983 / 10994

页数：12

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