An allenic Pauson-Khand-type reaction:: A reversal in π-bond selectivity and the formation of seven-membered rings

被引：119

作者：

Brummond, KM ^{[1
]}

Chen, HF

Fisher, KD

Kerekes, AD

Rickards, B

Sill, PC

Geib, SJ

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

[2] W Virginia Univ, Dept Chem, Morgantown, WV 26506 USA

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 11期

关键词：

D O I：

10.1021/ol025955w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Treatment of alkynyl allenes with [Rh(CO)(2)Cl](2) results in a formal [2 + 2 + 1] cycloaddition reaction. This reaction occurs with complete regioselectivity for a variety of substrates affording only 4-alkylidene cyclopentenones in good yields. Moreover, seven-membered rings have been prepared in high yields.

引用

页码：1931 / 1934

页数：4

共 47 条

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