Synthesis and characterization of MCM-41-type composite materials prepared from ZSM-5 zeolite

被引:46
作者
Song, Chun-Min [1 ]
Jiang, Jie [1 ]
Yan, Zi-feng [1 ]
机构
[1] China Univ Petr, CNPC, Key Lab Catalysis, State Key Lab Heavy Oil Proc, Dongying 257061, Peoples R China
关键词
micro; mesoporous composite material; ZSM-5; zeolite; mesoporous molecular sieves; alkaline treatment; soluble aluminosilicate species;
D O I
10.1007/s10934-007-9121-7
中图分类号
O69 [应用化学];
学科分类号
081704 [应用化学];
摘要
Micro/mesoporous composite materials with microporous and mesoporous double pores-size distribution were hydrothermally synthesized by using slurry or filtrate of alkali-treated ZSM-5 zeolite and were characterized by XRD, N-2 adsorption, FT-IR, TEM and so on. The XRD and TEM patterns indicate the composite materials possess ordered hexagonal structure. The sample MZ-B using filtrate of alkali-treated ZSM-5 zeolite hardly contains raw ZSM-5 particles. However, sample MZ-A originated from the slurry of alkali-treated ZSM-5 zeolite may contain some ZSM-5 crystallites, owing to the differences in concentration and time of alkaline treatment for ZSM-5 zeolite.
引用
收藏
页码:205 / 211
页数:7
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