Multiphoton absorbing materials: Molecular designs, characterizations, and applications

被引:1933
作者
He, Guang S. [1 ]
Tan, Loon-Seng [2 ]
Zheng, Qingdong [1 ]
Prasad, Paras N. [1 ]
机构
[1] SUNY Buffalo, Inst Lasers Photon & Biophoton, Buffalo, NY 14260 USA
[2] AF Res Lab, Mat Mfg Directorate, Polymer Branch, Wright Patterson AFB, OH 45433 USA
关键词
D O I
10.1021/cr050054x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
There has been a significant progress in the past decade in the study of multiphoton absorbing materials, such as the design and synthesis of two-photon absorbing materials with a very large cross section. Although it is still possible to further enhance the molecular 2PA cross section value by using an optimized molecular design strategy, for certain applications the two-photon-property requirement has basically been met with the new available materials. As such, there have been research on the major applications of multiphoton excitation (MPE) and multiphoton active materials. One of them, multiphoton pumped lasing have been used to achieve tunable frequency up-conversion of coherent light without the phase-matching requirement. It has the advantage of negligible initial attenuation for a strong signal. As such, it can be utilized for protection of optical sensors or human eyes from laser radiation-induced damage.
引用
收藏
页码:1245 / 1330
页数:86
相关论文
共 782 条
[31]   Upconverted lasing based on many-photon absorption:: an all dynamic description [J].
Baev, A ;
Gel'mukhanov, F ;
Rubio-Pons, O ;
Cronstrand, P ;
Ågren, H .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2004, 21 (02) :384-396
[32]   Nonlinear propagation of strong multi-mode fields [J].
Baev, A ;
Gel'mukhanov, F ;
Kimberg, V ;
Ågren, H .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2003, 36 (18) :3761-3774
[33]   General theory for pulse propagation in two-photon active media [J].
Baev, A ;
Gel'mukhanov, F ;
Macák, P ;
Luo, Y ;
Ågren, H .
JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (13) :6214-6220
[34]   Theoretical Simulations of clamping levels in optical power limiting [J].
Baev, Alexander ;
Norman, Patrick ;
Henriksson, Johan ;
Agren, Hans .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (42) :20912-20916
[35]   LOCATION OF THE LOWEST EVEN PARITY EXCITED SINGLET-STATE IN POLY (P-PHENYLENEVINYLENE) BY 2-PHOTON FLUORESCENCE SPECTROSCOPY [J].
BAKER, CJ ;
GELSEN, OM ;
BRADLEY, DDC .
CHEMICAL PHYSICS LETTERS, 1993, 201 (1-4) :127-131
[36]   White-light continuum Z-scan technique for nonlinear materials characterization [J].
Balu, M ;
Hales, J ;
Hagan, DJ ;
Van Stryland, EW .
OPTICS EXPRESS, 2004, 12 (16) :3820-3826
[37]   Two-photon absorption spectrum of 3-butoxycarbonylmethylurethane polydiacetylene thin films [J].
Banfi, G ;
Fortusini, D ;
Dainesi, P ;
Grando, D ;
Sottini, S .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (10) :4319-4323
[38]   2-PHOTON ABSORPTION AND 3RD-ORDER NONLINEARITIES IN GAAS QUANTUM DOTS [J].
BANYAI, L ;
LINDBERG, M ;
KOCH, SW .
OPTICS LETTERS, 1988, 13 (03) :212-214
[39]   The versatile thiophene: An overview of recent research on thiophene-based materials [J].
Barbarella, G ;
Melucci, M ;
Sotgiu, G .
ADVANCED MATERIALS, 2005, 17 (13) :1581-1593
[40]   Two-photon absorption in three-dimensional chromophores based on [2.2]-paracyclophane [J].
Bartholomew, GP ;
Rumi, M ;
Pond, SJK ;
Perry, JW ;
Tretiak, S ;
Bazan, GC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (37) :11529-11542