An interpenetrating coordination polymer containing weak hydrogen bonds and argentophilic interactions

被引：40

作者：

Duriska, MB ^{[1
]}

Batten, SR ^{[1
]}

Price, DJ ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2006年 / 59卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1071/CH05304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the coordination polymer [Ni(en)(2)][Ag(CN)(2)](2)[Ag-2(CN)(2)] (1;en=ethylenediamine) contains 2D (6,3) sheets in which trans-Ni(en)(2){Ag(CN)(2)}(2) moieties bridge between zigzag Ag(CN) chains. The sheets are puckered, and show 3-fold 2D -> 2D parallel interpenetration. The structure also contains weak N-H (.) (.) (.) pi(CN) and argentophilic Ag (.) (.) (.) Ag interactions between the 2D sheets.

引用

页码：26 / 29

页数：4

共 50 条

[1] A cubic (3,4)-connected net with large cavities in solvated [Cu-3(tpt)(4)](ClO4)(3) (tpt=2,4,6-tri(4-pyridyl)-1,3,5-triazine) [J].

Abrahams, BF ;

Batten, SR ;

Hamit, H ;

Hoskins, BF ;

Robson, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (15) :1690-1692

[2] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part II. Analysis of the Inorganic Crystal Structure Database (ICSD) [J].

Baburin, IA ;

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2452-2474

[3] 2 INTERPENETRATING 3D NETWORKS WHICH GENERATE SPACIOUS SEALED-OFF COMPARTMENTS ENCLOSING OF THE ORDER OF 20 SOLVENT MOLECULES IN THE STRUCTURES OF ZN(CN)(NO3)(TPT)(2/3)CENTER-DOT-SOLV (TPT=2,4,6-TRI(4-PYRIDYL)-1,3,5-TRIAZINE, SOLV=SIMILAR-TO-3/4C(2)H(2)CL(4)CENTER-DOT-3/4CH(3)OH OR SIMILAR-TO-3/2CHCL(3)CENTER-DOT-1/3CH(3)OH) [J].

BATTEN, SR ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5385-5386

[4]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[5]

2-Z

[6] Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide [J].

Batten, SR ;

Murray, KS .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :103-130

[7] Topology of interpenetration [J].

Batten, SR .

CRYSTENGCOMM, 2001, (18)

[8] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database [J].

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

CRYSTENGCOMM, 2004, 6 :377-395

[9] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[10] Developments in inorganic crystal engineering [J].

Brammer, L .

CHEMICAL SOCIETY REVIEWS, 2004, 33 (08) :476-489

← 1 2 3 4 5 →