An interpenetrating coordination polymer containing weak hydrogen bonds and argentophilic interactions

被引：40

作者：

Duriska, MB ^{[1
]}

Batten, SR ^{[1
]}

Price, DJ ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2006年 / 59卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1071/CH05304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the coordination polymer [Ni(en)(2)][Ag(CN)(2)](2)[Ag-2(CN)(2)] (1;en=ethylenediamine) contains 2D (6,3) sheets in which trans-Ni(en)(2){Ag(CN)(2)}(2) moieties bridge between zigzag Ag(CN) chains. The sheets are puckered, and show 3-fold 2D -> 2D parallel interpenetration. The structure also contains weak N-H (.) (.) (.) pi(CN) and argentophilic Ag (.) (.) (.) Ag interactions between the 2D sheets.

引用

页码：26 / 29

页数：4

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