2D hexagonal grids assembled into 3D nets via Ag•••Ag interactions

被引：16

作者：

Zhang, HX ^{[1
]}

Chen, ZN ^{[1
]}

Su, CY ^{[1
]}

Ren, C ^{[1
]}

Kang, BS ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1999年 / 29卷 / 12期

基金：

中国国家自然科学基金;

关键词：

cyanide bridge; Ag center dot center dot center dot Ag interaction; three-dimensional structure;

D O I：

10.1023/A:1009548705677

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A three-dimensional coordination polymer [Ni(en)(2)Ag-3(CN)(5)](n) (en = 1,2-diaminoethane) was synthesized and characterized by X-ray crystallography. It crystallizes in the triclinic space group <P(1)over bar>, a = 7.520(2) Angstrom, b = 8.194(2) Angstrom, c = 8.426(2) Angstrom, alpha = 65.35(3)degrees, beta = 69.57(3)degrees, gamma = 68.91(3)degrees, V = 428.0(2), Angstrom(3) Z = 1. The 2D hexagonal grids are constructed using cyanides as bridges, and the Ag ... Ag interactions between layers lead to a three-dimensional network.

引用

页码：1239 / 1243

页数：5

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