A remarkable example of co-crystallisation:: the crystal structure of the mononuclear and dinuclear diphenyl[2.2]paracyclophanylphosphine palladium(II) chloride complexes trans-[Pd{PPh2(C16H15)}2Cl2]•[Pd{PPh2(C16H15)}Cl2]2•0.6CH2Cl2

被引：18

作者：

Dyer, PW

Dyson, PJ ^{[1
]}

James, SL

Suman, P

Davies, JE

Martin, CM

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, Ctr Chem Synth, London SW7 2AY, England

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 13期

关键词：

D O I：

10.1039/a801863d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [Pd(cod)Cl-2] (cod = cycloocta-1,5-diene) with rac-diphenyl[2.2]paracyclophanylphosphine PPh2(C16H15) affords trans-[Pd{PPh2(C16H15)}(2)Cl-2] and [Pd{PPh2(C16H15)}Cl-2](2) in approximately equal yield which co-crystallise to form an unusual solid-state material.

引用

页码：1375 / 1376

页数：2

共 18 条

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