High efficiency solid-state sensitized heterojunction photovoltaic device

被引：65

作者：

Wang, Mingkui ^{[2
]}

Liu, Jingyuan ^{[1
]}

Cevey-Ha, Ngoc-Le ^{[2
]}

Moon, Soo-Jin ^{[2
]}

Liska, Paul ^{[2
]}

Humphry-Baker, Robin ^{[2
]}

Moser, Jacques-E. ^{[2
]}

Graetzel, Carole ^{[2
]}

Wang, Peng ^{[1
]}

Zakeeruddin, Shaik M. ^{[2
]}

Graetzel, Michael ^{[2
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, LPI, CH-1015 Lausanne, Switzerland

来源：

NANO TODAY | 2010年 / 5卷 / 03期

基金：

瑞士国家科学基金会;

关键词：

Solar cell; Sensitizer; Photoinduced absorption spectroscopy; Photovoltage transient spectroscopy; Charge recombination; PHOTOINDUCED ABSORPTION-SPECTROSCOPY; SOLAR-CELLS; ELECTRON-TRANSPORT; CHARGE-TRANSPORT; SPIRO-OMETAD; DYE; RECOMBINATION; PERFORMANCE; FILM; TOOL;

D O I：

10.1016/j.nantod.2010.04.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The high molar extinction coefficient heteroleptic ruthenium dye, NaRu(4,4'-bis(5-(hexylthio)thiophen-2-yl)-2,2'-bipyridine) (4-carboxylic acid-4'-carboxylate-2,2'-bipyridine) (NCS)(z), exhibits certified 5% electric power conversion efficiency at AM 1.5 solar irradiation (100 mWcm(-2)) in a solid-state dye-sensitized solar cell using 2,2',7,7'-tetrakis-(N,N-dipmethoxyphenylamine)-9,9'-spirobifluorene (spiro-MeOTAD) as the organic hole-transporting material. This demonstration elucidates a class of photovoltaic devices with potential for low-cost power generation. (C) 2010 Elsevier Ltd. All rights reserved.

引用

收藏

页码：169 / 174

页数：6

相关论文

共 28 条

[1] Charge separation in solid-state dye-sensitized heterojunction solar cells [J].

Bach, U ;

Tachibana, Y ;

Moser, JE ;

Haque, SA ;

Durrant, JR ;

Grätzel, M ;

Klug, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) :7445-7446

[2] Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].

Bach, U ;

Lupo, D ;

Comte, P ;

Moser, JE ;

Weissörtel, F ;

Salbeck, J ;

Spreitzer, H ;

Grätzel, M .

NATURE, 1998, 395 (6702) :583-585

[3] Photoinduced absorption spectroscopy as a tool in the study of dye-sensitized solar cells [J].

Boschloo, Gerrit ;

Hagfeldt, Anders .

INORGANICA CHIMICA ACTA, 2008, 361 (03) :729-734

[4] Dye-Sensitized Solar Cells with a High Absorptivity Ruthenium Sensitizer Featuring a 2-(Hexylthio)thiophene Conjugated Bipyridine [J].

Cao, Yiming ;

Bai, Yu ;

Yu, Qingjiang ;

Cheng, Yueming ;

Liu, Shi ;

Shi, Dong ;

Gao, Feifei ;

Wang, Peng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (15) :6290-6297

[5] Dye Regeneration by Spiro-MeOTAD in Solid State Dye-Sensitized Solar Cells Studied by Photoinduced Absorption Spectroscopy and Spectroelectrochemistry [J].

Cappel, Ute B. ;

Gibson, Elizabeth A. ;

Hagfeldt, Anders ;

Boschloo, Gerrit .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (15) :6275-6281

[6]

Chen C.Y., 2008, ANGEW CHEM, V120, P7452

[7] Multifunctionalized ruthenium-based supersensitizers for highly efficient dye-sensitized solar cells [J].

Chen, Chia-Yuan ;

Chen, Jian-Ging ;

Wu, Shi-Jhang ;

Li, Jheng-Ying ;

Wu, Chun-Guey ;

Ho, Kuo-Chuan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (38) :7342-7345

[8] Dye-sensitized solar cells with conversion efficiency of 11.1% [J].

Chiba, Yasuo ;

Islam, Ashraful ;

Watanabe, Yuki ;

Komiya, Ryoichi ;

Koide, Naoki ;

Han, Liyuan .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (24-28) :L638-L640

[9] Pore-Filling of Spiro-OMeTAD in Solid-State Dye Sensitized Solar Cells: Quantification, Mechanism, and Consequences for Device Performance [J].

Ding, I-Kang ;

Tetreault, Nicolas ;

Brillet, Jeremie ;

Hardin, Brian E. ;

Smith, Eva H. ;

Rosenthal, Samuel J. ;

Sauvage, Frederic ;

Graetzel, Michael ;

McGehee, Michael D. .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (15) :2431-2436

[10] Electron Transport and Recombination in Solid-State Dye Solar Cell with Spiro-OMeTAD as Hole Conductor [J].

Fabregat-Santiago, Francisco ;

Bisquert, Juan ;

Cevey, Le ;

Chen, Peter ;

Wang, Mingkui ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :558-562