Anodic polymerization of vinyl ethylene carbonate in Li-ion battery electrolyte

被引：47

作者：

Chen, GY ^{[1
]}

Zhuang, GV

Richardson, TJ

Liu, G

Ross, PN

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2005年 / 8卷 / 07期

关键词：

D O I：

10.1149/1.1921127

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A study of the anodic oxidation of vinyl ethylene carbonate (VEC) was conducted with post-mortem analysis of reaction products by attenuated total reflection Fourier transform infrared analysis and gel permeation chromatography (GPC). The half-wave potential (E1/2) for oxidation of VEC is ca. 3.6 V, producing a resistive film on the electrode surface. GPC analysis of the film on a gold electrode produced by anodization of a commercial Li-ion battery electrolyte containing 2% VEC at 4.1 V showed the presence of high molecular weight polymers. IR analysis indicated polycarbonates with alkyl carbonate rings linked by aliphatic methylene and methyl branches. (c) 2005 The Electrochemical Society.

引用

页码：A344 / A347

页数：4

共 24 条

[21] Electrochemical and infrared studies of the reduction of organic carbonates [J].