Synthesis of highly nitrogen-doped multi-walled carbon nanotubes

被引:170
作者
Glerup, M
Castignolles, M
Holzinger, M
Hug, G
Loiseau, A
Bernier, P
机构
[1] Univ Montpellier 2, Dynam Phases Condensees Grp, UMR5581, F-34095 Montpellier, France
[2] Off Natl Etud & Rech Aerosp, LEM, CNRS, UMR104, F-92322 Chatillon, France
关键词
D O I
10.1039/b303793b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present a new synthesis route for nitrogen doped carbon nanotubes (CNx) based on the aerosol method. Tubes with a record high concentration of nitrogen ( similar to 20 atom%) have been synthesized, confirmed by electron energy loss spectroscopy (EELS). A strong correlation between the N/C ratio and morphology of the tubes is observed and discussed.
引用
收藏
页码:2542 / 2543
页数:2
相关论文
共 24 条
[1]   Structural and electronic properties of composite BxCyNz nanotubes and heterojunctions [J].
Blase, X ;
Charlier, JC ;
De Vita, A ;
Car, R .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1999, 68 (03) :293-300
[2]   STABILITY AND BAND-GAP CONSTANCY OF BORON-NITRIDE NANOTUBES [J].
BLASE, X ;
RUBIO, A ;
LOUIE, SG ;
COHEN, ML .
EUROPHYSICS LETTERS, 1994, 28 (05) :335-340
[3]   Effects of nanodomain formation on the electronic structure of doped carbon nanotubes [J].
Carroll, DL ;
Redlich, P ;
Blase, X ;
Charlier, JC ;
Curran, S ;
Ajayan, PM ;
Roth, S ;
Ruhle, M .
PHYSICAL REVIEW LETTERS, 1998, 81 (11) :2332-2335
[4]   Origin of the large N is binding energy in X-ray photoelectron spectra of calcined carbonaceous materials [J].
Casanovas, J ;
Ricart, JM ;
Rubio, J ;
Illas, F ;
JimenezMateos, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (34) :8071-8076
[5]   Identification of electron donor states in N-doped carbon nanotubes [J].
Czerw, R ;
Terrones, M ;
Charlier, JC ;
Blase, X ;
Foley, B ;
Kamalakaran, R ;
Grobert, N ;
Terrones, H ;
Tekleab, D ;
Ajayan, PM ;
Blau, W ;
Rühle, M ;
Carroll, DL .
NANO LETTERS, 2001, 1 (09) :457-460
[6]   Incorporation of nitrogen in carbon nanotubes [J].
Droppa, R ;
Hammer, P ;
Carvalho, ACM ;
dos Santos, MC ;
Alvarez, F .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 299 :874-879
[7]   Synthesis of multi-walled carbon nanotubes and nano-fibres using the aerosol method with metal-ions as the catalyst precursors [J].
Glerup, M ;
Kanzow, H ;
Almairac, R ;
Castignolles, M ;
Bernier, P .
CHEMICAL PHYSICS LETTERS, 2003, 377 (3-4) :293-298
[8]   Large-scale synthesis and HRTEM analysis of single-walled B- and N-doped carbon nanotube bundles [J].
Golberg, D ;
Bando, Y ;
Bourgeois, L ;
Kurashima, K ;
Sato, T .
CARBON, 2000, 38 (14) :2017-2027
[9]   PREPARATION OF AMORPHOUS BORON-NITRIDE AND ITS CONVERSION TO A TURBOSTRATIC, TUBULAR FORM [J].
HAMILTON, EJM ;
DOLAN, SE ;
MANN, CM ;
COLIJN, HO ;
MCDONALD, CA ;
SHORE, SG .
SCIENCE, 1993, 260 (5108) :659-661
[10]   Atomic structure and electronic properties of single-wall carbon nanotubes probed by scanning tunneling microscope at room temperature [J].
Hassanien, A ;
Tokumoto, M ;
Kumazawa, Y ;
Kataura, H ;
Maniwa, Y ;
Suzuki, S ;
Achiba, Y .
APPLIED PHYSICS LETTERS, 1998, 73 (26) :3839-3841