Metal sensor of water soluble dansyl-modified thiacalix[4]arenes

被引:71
作者
Narita, M
Higuchi, Y
Hamada, F [1 ]
Kumagai, H
机构
[1] Akita Univ, Fac Engn & Resource Sci, Dept Mat Proc Engn & Appl Chem Environm, Akita 0100852, Japan
[2] Cosmo Res Inst, Chem Technol Lab, Satte, Saitama 3400193, Japan
关键词
D O I
10.1016/S0040-4039(98)01899-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The water soluble thiacalix[4]arene derivatives, which are modified with di- and tri-dansyl moieties, have been prepared to investigate their metal sensing abilities in aqueous solution. It is the first example that water soluble thiacalix[4]arene derivatives can detect metal cations directly in aqueous solution by variation of fluorescence intensity upon addition of a metal cation. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8687 / 8690
页数:4
相关论文
共 9 条
[1]  
CZARNIK AW, 1991, FRONTIERS SUPRAMOLEC
[2]  
HAMADA F, 1993, J INCLUS PHENOM MOL, V15, P273
[3]   High complexation ability of thiacalixarene with transition metal ions. The effects of replacing methylene bridges of tetra(p-t-butyl)calix[4]arenetetrol by epithio groups [J].
Iki, N ;
Morohashi, N ;
Narumi, F ;
Miyano, S .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (07) :1597-1603
[4]   Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base [J].
Kumagai, H ;
Hasegawa, M ;
Miyanari, S ;
Sugawa, Y ;
Sato, Y ;
Hori, T ;
Ueda, S ;
Kamiyama, H ;
Miyano, S .
TETRAHEDRON LETTERS, 1997, 38 (22) :3971-3972
[5]  
Lehn J. M., 1995, SUPRAMOLECULAR CHEM
[6]  
Rettig W., 1986, ANGEW CHEM INT EDIT, V98, P969, DOI [DOI 10.1002/ANGE.19860981104, 10.1002/anie.198609711, DOI 10.1002/ANIE.198609711]
[7]   HOST GUEST SENSORY SYSTEM OF DANSYL-MODIFIED BETA-CYCLODEXTRIN FOR DETECTING STEROIDAL COMPOUNDS BY DANSYL FLUORESCENCE [J].
UENO, A ;
MINATO, S ;
SUZUKI, I ;
FUKUSHIMA, M ;
OHKUBO, M ;
OSA, T ;
HAMADA, F ;
MURAI, K .
CHEMISTRY LETTERS, 1990, (04) :605-608
[8]  
UENO A, 1991, PHOTOCHEMISTRY ORG C
[9]  
Vicens J., 1991, CALIXARENES VERSATIL, V3