NOx removal process in pulsed corona discharge combined with TiO2 photocatalyst

被引：29

作者：

Daito, S ^{[1
]}

Tochikubo, F ^{[1
]}

Watanabe, T ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Dept Elect Eng, Hachioji, Tokyo 1900397, Japan

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS | 2001年 / 40卷 / 4A期

关键词：

removal of nitrogen oxides; coronas discharge; plasma-enhanced chemical reaction; TiO2; photocatalyst; photocatalytic reaction;

D O I：

10.1143/JJAP.40.2475

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The NOx removal process was studied experimentally in the pulsed corona discharge combined with the TiO2 photocatalytic reaction. First, the adsorption and desorption properties of NOx on the photocatalyst were investigated using UV irradiation from a black light without gas discharge. We found that NO2 was easily adsorbed on the photocatalyst surface, whereas NO was hardly adsorbed. Addition of water vapor enhanced the NO2 adsorption, Next, the relationship between the plasma-enhanced chemical reaction and the photocatalytic reaction was investigated using pulsed corona discharge with wire-plate-type electrodes positioned between two photocatalysts. The TiO2 photocatalyst efficiently assisted the increase of the NOx removal rate. The main role of the plasma-chemical reaction in this system is the oxidation of NO into NO2. A considerable part of NO2 is adsorbed on the photocatalyst surface, and is transformed to HNO3 through photocatalytic reaction with OH. HNO3 on the photocatalyst is hardly desorbed from the catalyst surface.

引用

页码：2475 / 2479

页数：5

共 15 条

[11] NOX REMOVAL BY A PIPE WITH NOZZLE-PLATE ELECTRODE CORONA DISCHARGE SYSTEM [J].

OHKUBO, T ;

KANAZAWA, S ;

NOMOTO, Y ;

CHANG, JS ;

ADACHI, T .

IEEE TRANSACTIONS ON INDUSTRY APPLICATIONS, 1994, 30 (04) :856-861

[12] Photocatalytic oxidation of ethylene to CO2 and H2O on ultrafine powdered TiO2 photocatalysts in the presence of O2 and H2O [J].

Park, DR ;

Zhang, JL ;

Ikeue, K ;

Yamashita, H ;

Anpo, M .

JOURNAL OF CATALYSIS, 1999, 185 (01) :114-119

[13]

SEINFELD JH, 1998, ATMOSPHERIC CHEM PHY, P1303

[14] OXIDATION OF NITROGEN MONOXIDE BY CORONA DISCHARGES .1. EFFECT OF DISCHARGE CONDITIONS [J].

TAMAKI, K ;

YOSHIDA, H ;

KATAYAMA, T ;

KAIDO, C .

NIPPON KAGAKU KAISHI, 1979, (11) :1582-1588

[15] RADIATION CHEMICAL-REACTIONS IN NOX AND SO2 REMOVALS FROM FLUE-GAS [J].

TOKUNAGA, O ;

SUZUKI, N .

RADIATION PHYSICS AND CHEMISTRY, 1984, 24 (01) :145-165

← 1 2 →