Synthesis and solid-state structure of [HB(3,5-Me2pz)3]GaFe(CO)4:: A compound with a short, two-electron Ga(I)→Fe dative bond

被引：24

作者：

Reger, DL ^{[1
]}

Garza, DG

Rheingold, AL

Yap, GPA

机构：

[1] Univ S Carolina, Dept Biochem & Chem, Columbia, SC 29208 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 16期

关键词：

D O I：

10.1021/om980333t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [HB(3,5-Me(2)pz)(3)]GaFe(CO)(4) has been synthesized in the reaction of [HB(3,5-Me(2)pz)(3)]GaMeCl and Na2Fe(C)(4) . (dioxane). The short Ga-Fe bond distance of 2.315(3) Angstrom is described as a normal two-electron dative bond (Ga --> Fe).

引用

页码：3624 / 3626

页数：3

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