A Salicylbisimine Cage Compound with High Surface Area and Selective CO2/CH4 Adsorption

被引：363

作者：

Mastalerz, Michael ^{[1
]}

Schneider, Markus W. ^{[1
]}

Oppel, Iris M. ^{[2
]}

Presly, Oliver ^{[3
]}

机构：

[1] Univ Ulm, Inst Organ Chem & Adv Mat 2, D-89081 Ulm, Germany

[2] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52074 Aachen, Germany

[3] Oxford Diffract Agilent Technol, Yarnton, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 05期

关键词：

adsorption; cage compounds; gas storage; microporous materials; Schiff bases; CONJUGATED MICROPOROUS POLYMER; DYNAMIC COVALENT SYNTHESIS; FREE-VOLUME; GAS; CRYSTALLINE; FRAMEWORKS; POROSITY; MINIMIZATION; MACROCYCLES; STABILITY;

D O I：

10.1002/anie.201005301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Preference for polar adsorbates: The crystalline porous organic cage compound shown has an exceptional high surface area (1566 m2ag -1) and selective gas uptake. The compound preferably adsorbs CO 2 (9.4 wta%) over methane (0.98 wta%). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1046 / 1051

页数：6

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