Tailoring aqueous solvents for organic reactions: Heck coupling reactions in high temperature water

被引：28

作者：

Gron, LU ^{[1
]}

Tinsley, AS ^{[1
]}

机构：

[1] Hendrix Coll, Dept Chem, Conway, AR 72032 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(98)02323-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

High temperature water is demonstrated to be an effective solvent for Heck coupling reactions of aromatic halides with cyclic alkenes without the addition of co-solvents or specialized ligands. Reactions in the presence of LiCl and quaternary ammonium salts indicate that the reaction takes place in the aqueous phase. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：227 / 230

页数：4

共 21 条

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