Effect of zeolite in surface discharge plasma on the decomposition of toluene

被引:41
作者
Oh, SM
Kim, HH
Ogata, A
Einaga, H
Futamura, S
Park, DW
机构
[1] Natl Inst Adv Ind Sci & Technol, Inst Environm Management Technol, AIST Tsukuba W, Tsukuba, Ibaraki 3058569, Japan
[2] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
关键词
surface discharge; toluene decomposition; zeolite; active oxygen;
D O I
10.1007/s10562-004-0782-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Toluene was decomposed in a surface discharge plasma reactor packed with various zeolites. The positioning effect of the zeolite bed was also investigated Reactor-B, in which the zeolite bed was located upstream, performed much better than Reactor-A, in which the zeolite bed was located downstream. Furthermore, the decomposition efficiency in Reactor-B increased with the capacity for toluene adsorption on zeolite, while that in Reactor-A did not. The toluene adsorbed in micropores was not decomposed effectively by direct electron impact, but was decomposed by active oxygen species generated in the plasma zone on the zeolite surface. A good correlation was also observed between toluene decomposition and ozone consumption in the downward-type reactor.
引用
收藏
页码:101 / 104
页数:4
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