Platinum electrodeposition mechanism during the reduction of platinum chloride complexes

被引：17

作者：

Kravtsov, VI ^{[1
]}

机构：

[1] St Petersburg State Univ, St Petersburg 199164, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2000年 / 36卷 / 11期

关键词：

D O I：

10.1007/BF02757696

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The nature and conditions of the occurrence of chemical and electrochemical steps of the electroreduction of chloride complexes of Pt(II) and Plt(IV) during the electrodeposition of platinum in the potential region corresponding to the double-layer segment of the charging curve are discussed. The relationship between the platinum electrodeposition mechanism and properties of produced electrolytic deposits of platinized platinum, in particular, their true surface area and its accessibility to various species is considered.

引用

页码：1209 / 1215

页数：7

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