Resonant x-ray-diffraction study of the charge ordering in NaV2O5 -: art. no. 104412

被引：21

作者：

Joly, Y ^{[1
]}

Grenier, S ^{[1
]}

Lorenzo, JE ^{[1
]}

机构：

[1] CNRS, Cristallog Lab, F-38042 Grenoble 9, France

来源：

PHYSICAL REVIEW B | 2003年 / 68卷 / 10期

关键词：

D O I：

10.1103/PhysRevB.68.104412

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We show that in the mixed-valence 3d transition-metal oxide NaV2O5 undergoing a structural transition, the low-temperature phase results from an effective ordering of the charge. This arrangement and the quantitative evaluation of the atomic charges are determined by using resonant x-ray scattering experiments further analyzed with the help of realistic calculations of the corresponding scattering factors. We have found that this reorganization concerns only a small fraction of electron and is necessary to reconcile all the experimental data.

引用

页数：4

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