Controllable Synthesis of Submillimeter Single-Crystal Monolayer Graphene Domains on Copper Foils by Suppressing Nucleation

被引：348

作者：

Wang, Hong ^{[1
,2
]}

Wang, Guanzhong ^{[1
,2
]}

Bao, Pengfei ^{[1
,2
]}

Yang, Shaolin ^{[1
,2
]}

Zhu, Wei ^{[1
,2
]}

Xie, Xing ^{[3
,4
]}

Zhang, Wen-Jun ^{[3
,4
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Dept Phys, Hefei 230026, Anhui, Peoples R China

[3] City Univ Hong Kong, Ctr Super Diamond & Adv Films COSDAF, Hong Kong, Hong Kong, Peoples R China

[4] City Univ Hong Kong, Dept Phys & Mat Sci, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 08期

关键词：

LARGE-AREA; HIGH-QUALITY; FILMS; GROWTH;

D O I：

10.1021/ja2105976

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Submillimeter single-crystal monolayer and multilayer graphene domains were prepared by an atmospheric pressure chemical vapor deposition method with suppressing nucleation on copper foils through an annealing procedure. A facile oxidation visualization method was applied to study the nucleation density and morphology of graphene domains on copper foils. Scanning electron microscopy, transmission electron microscopy, atomic force microscopy, polarized optical microscopy, and Raman spectra showed that the submillimeter graphene domains were monolayer single crystals.

引用

页码：3627 / 3630

页数：4

共 28 条

[1] GRAPHENE Pushing the boundaries [J].

Ajayan, Pulickel M. ;

Yakobson, Boris I. .

NATURE MATERIALS, 2011, 10 (06) :415-417

[2] Electronic confinement and coherence in patterned epitaxial graphene [J].

Berger, Claire ;

Song, Zhimin ;

Li, Xuebin ;

Wu, Xiaosong ;

Brown, Nate ;

Naud, Cecile ;

Mayou, Didier ;

Li, Tianbo ;

Hass, Joanna ;

Marchenkov, Atexei N. ;

Conrad, Edward H. ;

First, Phillip N. ;

de Heer, Wait A. .

SCIENCE, 2006, 312 (5777) :1191-1196

[3] Role of Kinetic Factors in Chemical Vapor Deposition Synthesis of Uniform Large Area Graphene Using Copper Catalyst [J].

Bhaviripudi, Sreekar ;

Jia, Xiaoting ;

Dresselhaus, Mildred S. ;

Kong, Jing .

NANO LETTERS, 2010, 10 (10) :4128-4133

[4]

Bonaccorso F, 2010, NAT PHOTONICS, V4, P611, DOI [10.1038/nphoton.2010.186, 10.1038/NPHOTON.2010.186]

[5] The electronic properties of graphene [J].

Castro Neto, A. H. ;

Guinea, F. ;

Peres, N. M. R. ;

Novoselov, K. S. ;

Geim, A. K. .

REVIEWS OF MODERN PHYSICS, 2009, 81 (01) :109-162

[6] Oxidation Resistance of Graphene-Coated Cu and Cu/Ni Alloy [J].

Chen, Shanshan ;

Brown, Lola ;

Levendorf, Mark ;

Cai, Weiwei ;

Ju, Sang-Yong ;

Edgeworth, Jonathan ;

Li, Xuesong ;

Magnuson, Carl W. ;

Velamakanni, Aruna ;

Piner, Richard D. ;

Kang, Junyong ;

Park, Jiwoong ;

Ruoff, Rodney S. .

ACS NANO, 2011, 5 (02) :1321-1327

[7] Influence of crystal habit on the compression and densification mechanism of ibuprofen [J].

Di Martino, P ;

Beccerica, M ;

Joiris, E ;

Palmieri, GF ;

Gayot, A ;

Martelli, S .

JOURNAL OF CRYSTAL GROWTH, 2002, 243 (02) :345-355

[8] Graphene Nucleation on Transition Metal Surface: Structure Transformation and Role of the Metal Step Edge [J].

Gao, Junfeng ;

Yip, Joanne ;

Zhao, Jijun ;

Yakobson, Boris I. ;

Ding, Feng .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (13) :5009-5015

[9] The rise of graphene [J].

Geim, A. K. ;

Novoselov, K. S. .

NATURE MATERIALS, 2007, 6 (03) :183-191

[10] Grains and grain boundaries in single-layer graphene atomic patchwork quilts [J].

Huang, Pinshane Y. ;

Ruiz-Vargas, Carlos S. ;

van der Zande, Arend M. ;

Whitney, William S. ;

Levendorf, Mark P. ;

Kevek, Joshua W. ;

Garg, Shivank ;

Alden, Jonathan S. ;

Hustedt, Caleb J. ;

Zhu, Ye ;

Park, Jiwoong ;

McEuen, Paul L. ;

Muller, David A. .

NATURE, 2011, 469 (7330) :389-+

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