Iridium(I)-catalysed tandem hydrosilylation-protodesilylation of imines

被引：24

作者：

Field, LD

Messerle, BA ^{[1
]}

Rumble, SL

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] Univ New S Wales, Sch Chem, Kensington, NSW 2033, Australia

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 2005卷 / 14期

关键词：

hydrosilylation; imines; iridium; solvent effects; homogeneous catalysis;

D O I：

10.1002/ejoc.2005000168

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of alkylsilanes, the cationic Ir-I complex [{Ir[bis(pyrazol-1-yl)methane](CO)(2)}BPh4] (1) catalyses the reduction of a range of imines, including N-alkyl and N-aryl imines, and both aldimines and ketimines. Excellent conversions directly to the product amines are achieved rapidly at room temperature in methanol solution. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

引用

收藏

页码：2881 / 2883

页数：3

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