Hydrothermal synthesis and structural characterization of a coordination polymer containing heptanuclear Co7(μ3-OH)8 clusters

被引：55

作者：

Chiang, RK ^{[1
]}

Huang, CC

Wur, CS

机构：

[1] Far E Coll, Dept Chem Engn, Tainan 744, Taiwan

[2] Far E Coll, Dept Elect Mat, Tainan 744, Taiwan

[3] Natl Cheng Kung Univ, Dept Phys, Tainan 700, Taiwan

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 13期

关键词：

D O I：

10.1021/ic010164w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermally synthesized Co-7(u(3)-OH)(8)(mu -ox)(3)-(mu -ppz)(3) contains heptanuclear hydroxo-bridged Co-(II) clusters in the form of corner-fused double cubanes: Each cluster is further bridged by six oxalate (di) and Six: piperazine (ppi) ligands with 12 other clusters into a 3-D structure.

引用

收藏

页码：3237 / +

页数：4

相关论文

共 27 条

[1] Cobalt(III) complexes containing incomplete C3O4 or complete Co4O4 cubane core [J].

Ama, T ;

Rashid, MM ;

Yonemura, T ;

Kawaguchi, H ;

Yasui, T .

COORDINATION CHEMISTRY REVIEWS, 2000, 198 :101-116

[2]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[3]

2-Z

[4] Structural studies of heptanuclear cobalt complexes and larger oligomers based on heptanuclear fragments [J].

Brechin, EK ;

Graham, A ;

Parkin, A ;

Parsons, S ;

Seddon, AM ;

Winpenny, REP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (19) :3242-3252

[5] Synthesis, structural characterisation and preliminary magnetic studies of a tetraicosanuclear cobalt coordination complex [J].

Brechin, EK ;

Harris, SG ;

Harrison, A ;

Parsons, S ;

Whittaker, AG ;

Winpenny, REP .

CHEMICAL COMMUNICATIONS, 1997, (07) :653-654

[6] Desolvating cubes and linking prisms: Routes to high-nuclearity cobalt complexes [J].

Brechin, EK ;

Harris, SG ;

Parsons, S ;

Winpenny, REP .

CHEMICAL COMMUNICATIONS, 1996, (12) :1439-1440

[7] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[8]

Decurtins S, 1999, COORDIN CHEM REV, V190, P841

[9] DIMERIZATION OF THE [CO(III)2(OH)2] CORE TO THE 1ST EXAMPLE OF A [CO(III)4O4] CUBANE - POTENTIAL INSIGHTS INTO PHOTOSYNTHETIC WATER OXIDATION [J].

DIMITROU, K ;

FOLTING, K ;

STREIB, WE ;

CHRISTOU, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6432-6433

[10] LEWIS BASICITY OF THE [CO4O4](4+) CUBANE CORE - PREPARATION OF A MIXED-VALENCE (4CO(II),4CO(III)) CLUSTER WITH AN UNUSUAL [CO-8(MU(4)-O)(4)](2+) CORE, AND NEW [CO4O3(OH)](5+) AND [CO4O2(OH)(2)](6+) CUBANE COMPLEXES [J].

DIMITROU, K ;

FOLTING, K ;

STREIB, WE ;

CHRISTOU, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (11) :1385-1386