Hydrothermal synthesis and structural characterization of a coordination polymer containing heptanuclear Co7(μ3-OH)8 clusters

被引:55
作者
Chiang, RK [1 ]
Huang, CC
Wur, CS
机构
[1] Far E Coll, Dept Chem Engn, Tainan 744, Taiwan
[2] Far E Coll, Dept Elect Mat, Tainan 744, Taiwan
[3] Natl Cheng Kung Univ, Dept Phys, Tainan 700, Taiwan
关键词
D O I
10.1021/ic010164w
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The hydrothermally synthesized Co-7(u(3)-OH)(8)(mu -ox)(3)-(mu -ppz)(3) contains heptanuclear hydroxo-bridged Co-(II) clusters in the form of corner-fused double cubanes: Each cluster is further bridged by six oxalate (di) and Six: piperazine (ppi) ligands with 12 other clusters into a 3-D structure.
引用
收藏
页码:3237 / +
页数:4
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