Sterically protected 1,2,3-dithiazolyl radicals: preparation and structural characterization of 4-chloro-5-pentafluorophenyl-1,2,3-dithiazolyl

被引：67

作者：

Barclay, TM

Beer, L

Cordes, AW

Oakley, RT ^{[1
]}

Preuss, KE

Taylor, NJ

Reed, RW

机构：

[1] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada

[2] Univ Arkansas, Dept Chem & Biochem, Fayetteville, AR 72701 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 06期

关键词：

D O I：

10.1039/a809951k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Steric protection afforded by a pentafluorophenyl group at the 5-position facilitates the first isolation and structural characterization of a monocyclic 1,2,3-dithiazolyl as its S-S bonded dimer.

引用

页码：531 / 532

页数：2

共 28 条

[1] SYNTHESIS AND REACTIONS OF 4,5-DICHLORO-1,2,3-DITHIAZOLIUM CHLORIDE [J].

APPEL, R ;

JANSSEN, H ;

SIRAY, M ;

KNOCH, F .

CHEMISCHE BERICHTE-RECUEIL, 1985, 118 (04) :1632-1643

[2] X-RAY CRYSTAL-STRUCTURES OF THE 1,3,2-BENZODITHIAZOLYL DIMER AND 1,3,2-BENZODITHIAZOLIUM CHLORIDE SULFUR-DIOXIDE SOLVATE - COMPARISON OF THE MOLECULAR AND ELECTRONIC-STRUCTURES OF THE 10-PI-ELECTRON C6H4S2N+ CATION AND THE C6H4S2N. RADICAL AND DIMER AND A STUDY OF THE VARIABLE-TEMPERATURE MAGNETIC-BEHAVIOR OF THE RADICAL [J].

AWERE, EG ;

BURFORD, N ;

HADDON, RC ;

PARSONS, S ;

PASSMORE, J ;

WASZCZAK, JV ;

WHITE, PS .

INORGANIC CHEMISTRY, 1990, 29 (23) :4821-4830

[3]

BANISTER AJ, 1992, CHEM INORGANIC RING, P295

[4] Benzo-bridged bis(1,2,3-dithiazoles) and their selenium analogues. Preparation, molecular and electronic structures, and redox chemistry [J].

Barclay, TM ;

Cordes, AW ;

Goddard, JD ;

Mawhinney, RC ;

Oakley, RT ;

Preuss, KE ;

Reed, RW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (50) :12136-12141

[5] 1,1′,2,2′,3,3′-tetrathiadiazafulvalenes;: preparation and characterisation of trans-[ClCNS2C=CS2NCCl] [J].

Barclay, TM ;

Cordes, AW ;

Oakley, RT ;

Preuss, KE ;

Reed, RW .

CHEMICAL COMMUNICATIONS, 1998, (09) :1039-1040

[6] Preparation and characterization of a neutral π-radical molecular conductor [J].

Barclay, TM ;

Cordes, AW ;

Haddon, RC ;

Itkis, ME ;

Oakley, RT ;

Reed, RW ;

Zhang, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (05) :969-976

[7] Redox, magnetic, and structural properties of 1,3,2-dithiazolyl radicals.: A case study on the ternary heterocycle S3N5C4 [J].

Barclay, TM ;

Cordes, AW ;

George, NA ;

Haddon, RC ;

Itkis, ME ;

Mashuta, MS ;

Oakley, RT ;

Patenaude, GW ;

Reed, RW ;

Richardson, JF ;

Zhang, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (02) :352-360

[8] Molecular materials from 1,3,2-dithiazolyls. Solid-state structures and magnetic properties of 2,3-naphthalene and quinoxaline derivatives [J].

Barclay, TM ;

Cordes, AW ;

George, NA ;

Haddon, RC ;

Oakley, RT ;

Palstra, TTM ;

Patenaude, GW ;

Reed, RW ;

Richardson, JF ;

Zhang, HZ .

CHEMICAL COMMUNICATIONS, 1997, (09) :873-874

[9] SYNTHESIS, STRUCTURE, AND SOME PROPERTIES OF 1,2,3-BENZODITHIAZOLIUM SALTS [J].

BATS, JW ;

FUESS, H ;

WEBER, KL ;

ROESKY, HW .

CHEMISCHE BERICHTE-RECUEIL, 1983, 116 (05) :1751-1755

[10]

BOERE RT, 1995, J AM CHEM SOC, V117, P4775

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