Cooperative catalysis with chiral Bronsted acid-Rh2(OAC)4:: Highly enantioselective three-component reactions of diazo compounds with alcohols and imines

被引：320

作者：

Hu, Wenhao ^{[1
]}

Xu, Xinfang ^{[1
]}

Zhou, Jing ^{[1
]}

Liu, Wei-Jun ^{[2
,3
]}

Huang, Haoxi ^{[1
]}

Hu, Juan ^{[1
]}

Yang, Liping ^{[1
]}

Gong, Liu-Zhu ^{[2
,3
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China

[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China

[3] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 25期

关键词：

D O I：

10.1021/ja801755z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An asymmetric three-component reaction of diazo compounds and alcohols with imines catalyzed cooperatively by a rhodium complex and a chiral Bronsted acid provides a general and efficient entry to beta-amino-a-hydroxyl acid derivatives in high yields with excellent stereoselectivities.

引用

页码：7782 / +

页数：3

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