Utilization of Direct and Diffuse Sunlight in a Dye-Sensitized Solar Cell - Silicon Photovoltaic Hybrid Concentrator System

被引:50
作者
Barber, Greg D. [1 ]
Hoertz, Paul G. [1 ]
Lee, Seung-Hyun Anna [1 ]
Abrarns, Neal M. [1 ]
Mikulca, Janine [1 ]
Mallouk, Thomas E. [1 ]
Liska, Paul [1 ]
Zakeeruddin, Shaik M. [2 ]
Graetzel, Michael [2 ]
Ho-Baillie, Anita [3 ]
Green, Martin A. [3 ]
机构
[1] Penn State Univ, Dept Chem, University Pk, PA 16801 USA
[2] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Lausanne, Switzerland
[3] Univ New S Wales, ARC Photovolta Ctr Excellence, Sch Photovolta & Renewable Energy Engn, Sydney, NSW, Australia
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2011年 / 2卷 / 06期
关键词
CONVERSION EFFICIENCY; LIGHT; ENERGY;
D O I
10.1021/jz200112m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The concept of a tandem hybrid concentrator solar module was demonstrated from a dye-sensitized TiO2 solar cell (DSSCs) and a silicon p-n junction solar cell. The test system employed DSSC and Si cells with indoor AM1.5G efficiencies of 9.1 and 18.1%, respectively. Two different optical filters were used to selectively reflect and concentrate near-infrared light from the DSSC onto the Si cell. On the basis of outdoor testing in a 2 x concentrator reflector arrangement, the tandem system generated 93 and 96% of the output power of directly illuminated Si cells under altostratus/cirrostratus and clear sky irradiances, respectively, despite a DSSC-to-Si active area ratio of only 0.92. Similar performance is expected at higher (5-10 x) concentration ratios. The hybrid arrangement of visible- and IR-absorbing solar cells addresses the problem of lower performance of conventional concentrators under diffuse irradiance conditions. These proof-of-concept results suggest that system level efficiencies approaching 20% should be achievable.
引用
收藏
页码:581 / 585
页数:5
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