Relation between substrate surface morphology and microcrystalline silicon solar cell performance

被引:165
作者
Python, Martin [1 ]
Vallat-Sauvain, Evelyne [1 ]
Bailat, Julien [1 ]
Domine, Didier [1 ]
Fesquet, Luc [1 ]
Shah, Arvind [1 ]
Ballif, Christophe [1 ]
机构
[1] Inst Microtechnol IMT, Thin Film Silicon & Photovolta Lab, Neuchatel, Switzerland
关键词
silicon; solar cells; photovoltaics; TEM/STEM; microcrystallinity; porosity;
D O I
10.1016/j.jnoncrysol.2007.09.084
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In the present paper, the structural and electrical performances of microcrystalline silicon (mu c-Si:H) single junction solar cells co-deposited on a series of substrates having different surface morphologies varying from V-shaped to U-shaped valleys, are analyzed. Transmission electron microscopy (TEM) is used to quantify the density of cracks within the cells deposited on the various substrates. Standard 1 sun, variable illumination measurements (VIM) and Dark J(V) measurements are performed to evaluate the electrical performances of the devices. A marked increase of the reverse saturation current density (J(0)) is observed for increasing crack densities. By introducing a novel equivalent circuit taking into account such cracks as non-linear shunts, the authors are able to relate the magnitude of the decrease of V-oc and FF to the increasing density of cracks. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:2258 / 2262
页数:5
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