One-step ultrasonic synthesis of water-soluble carbon nanoparticles with excellent photoluminescent properties

被引:786
作者
Li, Haitao [1 ,2 ]
He, Xiaodie [1 ,2 ]
Liu, Yang [1 ,2 ]
Huang, Hui [1 ,2 ]
Lian, Suoyuan [1 ,2 ]
Lee, Shuit-Tong [3 ]
Kang, Zhenhui [1 ,2 ]
机构
[1] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Peoples R China
[2] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China
[3] City Univ Hong Kong, Ctr Super Diamond & Adv Films, Hong Kong, Hong Kong, Peoples R China
关键词
INDUCED FLUORESCENCE DETECTION; QUANTUM DOTS; CAPILLARY-ELECTROPHORESIS; IN-VIVO; NANOCRYSTALS; NANOTUBES; CELLS; MICROSCOPY; GRAPHITE; SPHERES;
D O I
10.1016/j.carbon.2010.10.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Monodispersed water-soluble fluorescent carbon nanoparticles (CNPs) were synthesized directly from glucose by a one-step alkali or acid assisted ultrasonic treatment. The CNPs were characterized by transmission electron microscopy, optical fluorescent microscopy, fluorescent spectrophotometry, fourier transform infrared spectrophotometry and ultraviolet-visible spectrophotometry. The results showed that the particle surfaces were rich in hydroxyl groups, giving them high hydrophilicity. The CNPs could emit bright and colorful photoluminescence covering the entire visible-to-near infrared (NIR) spectral range. Notably, the NIR emission of the CNPs could be obtained by NIR excitation. Furthermore, these CNPs also had excellent up-conversion fluorescent properties. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:605 / 609
页数:5
相关论文
共 35 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   Ultrasensitive detection of closely related angiotensin I peptides doing capillary electrophoresis with near-infrared laser-induced fluorescence detection [J].
Baars, MJ ;
Patonay, G .
ANALYTICAL CHEMISTRY, 1999, 71 (03) :667-671
[3]   Folate-receptor-mediated delivery of InP quantum dots for bioimaging using confocal and two-photon microscopy [J].
Bharali, DJ ;
Lucey, DW ;
Jayakumar, H ;
Pudavar, HE ;
Prasad, PN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (32) :11364-11371
[4]   Isolation and characterization of fluorescent nanoparticles from pristine and oxidized electric arc-produced single-walled carbon nanotubes [J].
Bottini, M ;
Balasubramanian, C ;
Dawson, MI ;
Bergamaschi, A ;
Bellucci, S ;
Mustelin, T .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (02) :831-836
[5]   Surface functionalized carbogenic quantum dots [J].
Bourlinos, Athanasios B. ;
Stassinopoulos, Andreas ;
Anglos, Demetrios ;
Zboril, Radek ;
Karakassides, Michael ;
Giannelis, Emmanuel P. .
SMALL, 2008, 4 (04) :455-458
[6]   Carbon dots for multiphoton bioimaging [J].
Cao, Li ;
Wang, Xin ;
Meziani, Mohammed J. ;
Lu, Fushen ;
Wang, Haifang ;
Luo, Pengju G. ;
Lin, Yi ;
Harruff, Barbara A. ;
Veca, L. Monica ;
Murray, Davoy ;
Xie, Su-Yuan ;
Sun, Ya-Ping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (37) :11318-+
[7]   Quantum dot bioconjugates for ultrasensitive nonisotopic detection [J].
Chan, WCW ;
Nie, SM .
SCIENCE, 1998, 281 (5385) :2016-2018
[8]   Fluorescent CdSe/ZnS nanocrystal-peptide conjugates for long-term, nontoxic imaging and nuclear targeting in living cells [J].
Chen, FQ ;
Gerion, D .
NANO LETTERS, 2004, 4 (10) :1827-1832
[9]   Bromide-sulfur interchange: Ion chromatographic determination of total reduced thiol levels in plasma [J].
Chitre, Sneha A. ;
Lobo, Grace-Ann M. ;
Rathod, Spandan M. ;
Smith, Robert B. ;
Leslie, Ray ;
Livingstone, Callum ;
Davis, James .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2008, 864 (1-2) :173-177
[10]   Applications of Nanoparticles in Biology [J].
De, Mrinmoy ;
Ghosh, Partha S. ;
Rotello, Vincent M. .
ADVANCED MATERIALS, 2008, 20 (22) :4225-4241