共 43 条
L-Proline amide-catalyzed direct asymmetric aldol reaction of aldehydes with chloroacetone
被引:77
作者:

He, L
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机构: Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

Tang, Z
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机构: Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

Cun, LF
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机构: Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

Mi, AQ
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机构: Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

Jiang, YZ
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机构: Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

Gong, LZ
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机构:
Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China
机构:
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
[4] China W Normal Univ, Coll Chem & Chem Engn, Nanchong 637002, Peoples R China
基金:
中国国家自然科学基金;
关键词:
organocatalyst;
L-proline amides;
direct aldol reaction;
asymmetric catalysis;
chloroacetone;
D O I:
10.1016/j.tet.2005.09.061
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
L-Proline amides were evaluated for catalyzing the direct aldol reaction of 4-nitrobenzaldchyde with chloroacetone. The presence of 30 mol% (S)-pyrrolidine-2-carboxylic acid (2,4,6-trimethyl-phenyl)-amide catalyzed the direct aldol reactions of a range of aldehydes with chloroacetone to give anti-alpha-chloro-beta-hydroxyketones with high regio-, diastereo- and enantioselectivity. (c) 2005 Elsevier Ltd. All rights reserved.
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页码:346 / 351
页数:6
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