High-Power and High-Energy-Density Flexible Pseudocapacitor Electrodes Made from Porous CuO Nanobelts and Single-Walled Carbon Nanotubes

被引:334
作者
Zhang, Xiaojun [1 ,2 ]
Shi, Wenhui [1 ]
Zhu, Jixin [1 ]
Kharistal, Daniel Julian [1 ]
Zhao, Weiyun [1 ]
Lalia, Boor Singh [3 ]
Hng, Huey Hoon [1 ]
Yan, Qingyu [1 ,3 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[2] Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu 241000, Peoples R China
[3] Nanyang Technol Univ, Energy Res Inst NTU, Singapore 637459, Singapore
基金
中国国家自然科学基金;
关键词
CuO; porous nanobelts; pseudocapacitor electrodes; power density; energy density; flexible electrode; OXIDE; SUPERCAPACITORS; COMPOSITES; DESIGN; HYBRID; FILM; NANOSHEETS;
D O I
10.1021/nn1030719
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a simple wet-chemical process to prepare porous CuO nanobelts (NBs) with high surface area and small crystal grains. These CuO NBs were mixed with carbon nanotubes in an appropriate ratio to fabricate pseudocapacitor electrodes with stable cycling performances, which showed a series of high energy densities at different power densities, for example, 130.2, 92, 44, 25, and 20.8 W h kg(-1) at power densities of 1.25, 6.25, 25, and 50 k Wh kg(-1), respectively. CuO-on-single-walled carbon nanotube (SWCNT) flexible hybrid electrodes were also fabricated using the SWCNT films as current collectors. These flexible electrodes showed much higher specific capacitance than that of electrodes made of pure SWCNTs and exhibited more stable cycling performance, for example, effective specific capacitances of >62 F g(-1) for the hybrid electrodes after 1000 cycles in 1 M LiPF6/EC:DEC at a current density of 5 A g(-1) and specific capacitance of only 23.6 F g(-1) for pure SWCNT electrodes under the same testing condition.
引用
收藏
页码:2013 / 2019
页数:7
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