A Sodalite-Type Porous Metal-Organic Framework with Polyoxometalate Templates: Adsorption and Decomposition of Dimethyl Methylphosphonate

被引：429

作者：

Ma, Feng-Ji ^{[1
]}

Liu, Shu-Xia ^{[1
]}

Sun, Chun-Yan ^{[1
]}

Liang, Da-Dong ^{[1
]}

Ren, Guo-Jian ^{[1
]}

Wei, Feng ^{[1
]}

Chen, Ya-Guang ^{[1
]}

Su, Zhong-Min ^{[1
]}

机构：

[1] NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 12期

关键词：

BUILDING-BLOCKS; WATER-TOLERANT; CRYSTAL; SEPARATION; CLUSTERS; SORPTION; SOLIDS;

D O I：

10.1021/ja109659k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A sodalite-type porous metal organic framework with polyoxometalate templates, H-3[(CU4Cl)(3)(BTC)(8)](2)-[PW12O40]center dot(C4H12N)(6)center dot 3H(2)O (NENU-11; BTC = 1,3, 5-benzenetricarboxylate), was obtained by a hydrothermal reaction. As a reasonable candidate for eliminating nerve gas, NENU-11 displays good adsorption behavior for dimethyl methylphosphonate (15.5 molecules per formula unit). In virtue of the catalytic activity of polyoxometalate guests, this nerve gas mimic could be facilely decomposed by a hydrolysis reaction.

引用

页码：4178 / 4181

页数：4

共 46 条

[31] POLYOXOMETALATE CHEMISTRY - AN OLD FIELD WITH NEW DIMENSIONS IN SEVERAL DISCIPLINES [J].