Structure and electronic properties of an asymmetric thiolate-bridged binuclear complex:: a model for the active site of acetyl CoA synthase

被引：40

作者：

Wang, Q

Blake, AJ

Davies, ES

McInnes, EJL

Wilson, C

Schröder, M

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Manchester, Dept Chem, EPSRC EPR Serv Ctr, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 24期

关键词：

D O I：

10.1039/b310183e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The asymmetric binuclear complex [(dppe)Ni(mu-'S, S')Ni(L)](PF6)(2)[L = (N,N'-diethyl-3,7-diazanonane-1,9-dithiolato)(2-)] shows a reversible one-electron reduction to afford a mixed-valent Ni(II)-Ni(I) species; the reduced complex has been characterised by EPR spectroscopy and mimics the redox active Ni-p site in the active A-cluster of acetyl coenzyme A synthase.

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页码：3012 / 3013

页数：2

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