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Structure and electronic properties of an asymmetric thiolate-bridged binuclear complex:: a model for the active site of acetyl CoA synthase
被引:40
作者:
Wang, Q
Blake, AJ
Davies, ES
McInnes, EJL
Wilson, C
Schröder, M
机构:
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Manchester, Dept Chem, EPSRC EPR Serv Ctr, Manchester M13 9PL, Lancs, England
关键词:
D O I:
10.1039/b310183e
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The asymmetric binuclear complex [(dppe)Ni(mu-'S, S')Ni(L)](PF6)(2)[L = (N,N'-diethyl-3,7-diazanonane-1,9-dithiolato)(2-)] shows a reversible one-electron reduction to afford a mixed-valent Ni(II)-Ni(I) species; the reduced complex has been characterised by EPR spectroscopy and mimics the redox active Ni-p site in the active A-cluster of acetyl coenzyme A synthase.
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页码:3012 / 3013
页数:2
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