A simple single-step synthesis of [(Tc3H3)-Tc-99(CO)(12)] from [(TcO4)-Tc-99](-) and its x-ray crystal structure. Application to the production of no-carrier added [(Re3H3)-Re-188(CO)(12)]

被引：34

作者：

Alberto, R

Schibli, R

Schubiger, PA

Abram, U

Hubener, R

Berke, H

Kaden, TA

机构：

[1] UNIV TUBINGEN,INST INORGAN CHEM,D-72076 TUBINGEN,GERMANY

[2] UNIV ZURICH,INST INORGAN CHEM,CH-8057 ZURICH,SWITZERLAND

[3] UNIV BASEL,INST INORGAN CHEM,CH-4056 BASEL,SWITZERLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 11期

关键词：

D O I：

10.1039/cc9960001291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of no-carrier added [(ReO4)-Re-188](-) (ng range) in thf-[NBu(4)]Cl with BH3 . thf under an atmosphere of CO yields [(ReCl3)-Re-188(CO)(3)](2-) and [Re-188(3)(mu-H)(3)(CO)(12)]; under similar conditions as with [(ReO4)-Re-188](-), the first mu-hydrido-bridged Tc-99 hydride carbonyl complex is prepared and structurally characterised.

引用

页码：1291 / 1292

页数：2

共 24 条

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