Poly(amidoamine)-dendrimer-stabilized Pd(0) nanoparticles as a catalyst for the Suzuki reaction

被引：142

作者：

Pittelkow, M

Moth-Poulsen, K

Boas, U

Christensen, JB

机构：

[1] Univ Copenhagen, Chem Lab 2, DK-2100 Copenhagen, Denmark

[2] Univ Copenhagen, Nanosci Ctr, DK-1123 Copenhagen, Denmark

[3] Danish Vet Inst, DK-1790 Copenhagen, Denmark

来源：

LANGMUIR | 2003年 / 19卷 / 18期

关键词：

D O I：

10.1021/la0348822

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Suzuki cross-coupling reactions between aryl halides (or triflates) and boronic acid derivatives are one of the most important palladium-catalyzed reactions. This paper discusses the examination of the Pd(0) nanoparticles by TEM. It also details the calculation of the turnover numbers (TONs) and the turnover frequencies (TOFs) as mol product/mol catalyst and mol product/(mol catalyst·hr).

引用

页码：7682 / 7684

页数：3

共 34 条

[1]

Baars MWPL, 2000, TOP CURR CHEM, V210, P131

[2] Poly(amidoamine) dendrimer-templated nanocomposites. 1. Synthesis of zerovalent copper nanoclusters [J].