The 'dendritic effect' on the electrochemical properties of an encapsulated redox center: correlation of size exclusion chromatography data and redox reversibility of electrochemically active homoleptic and heteroleptic ruthenium(II)-bis(terpyridine) metallodendrimers

被引：19

作者：

Chow, HF ^{[1
]}

Chan, IYK ^{[1
]}

Fung, PS ^{[1
]}

Mong, TKK ^{[1
]}

Nongrum, MF ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

TETRAHEDRON | 2001年 / 57卷 / 08期

关键词：

metallodendrimers; cyclic voltammetry;

D O I：

10.1016/S0040-4020(00)01124-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of homoleptic and heteroleptic ruthenium(II)-bis(terpyridine) metallodendrimers bearing an electrochemically active unit encapsulated in a polyether dendritic envelope was prepared. Cyclic voltammetry studies on these dendrimers indicated the decrease of redox reversibility correlated well to the size exclusion chromatography data. The results suggest that electron transfer between the electrode and the buried redox center does not have any orientation preference. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1565 / 1572

页数：8

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