Rh(II)-catalyzed Sommelet-Hauser rearrangement

被引：53

作者：

Liao, Mingyi

Peng, Lingling

Wang, Jianbo ^{[1
]}

机构：

[1] Peking Univ, BNLMS, Beijing 100871, Peoples R China

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 05期

关键词：

D O I：

10.1021/ol703058p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic Sommelet-Hauser rearrangement is reported. The Rh(II)-catalyzed reaction of aryldiazoacetates with ethyl benzylthioacetate affords Sommelet-Hauser rearrangement products in good to excellent yields. This reaction provides a reliable and efficient way to introduce a substituent to the ortho position of arylacetates.

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收藏

页码：693 / 696

页数：4

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