Rh(II)-catalyzed Sommelet-Hauser rearrangement

被引:52
作者
Liao, Mingyi
Peng, Lingling
Wang, Jianbo [1 ]
机构
[1] Peking Univ, BNLMS, Beijing 100871, Peoples R China
关键词
D O I
10.1021/ol703058p
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Catalytic Sommelet-Hauser rearrangement is reported. The Rh(II)-catalyzed reaction of aryldiazoacetates with ethyl benzylthioacetate affords Sommelet-Hauser rearrangement products in good to excellent yields. This reaction provides a reliable and efficient way to introduce a substituent to the ortho position of arylacetates.
引用
收藏
页码:693 / 696
页数:4
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