Heterolytic Cleavage of Dihydrogen by "Frustrated Lewis Pairs" Comprising Bis(2,4,6-tris(trifluoromethyl)phenyl)borane and Amines: Stepwise versus Concerted Mechanism

被引：85

作者：

Lu, Zhenpin ^{[1
]}

Cheng, Zhonghua ^{[1
]}

Chen, Zhenxia ^{[1
]}

Weng, Linhong ^{[1
]}

Li, Zhen Hua ^{[1
]}

Wang, Huadong ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期

关键词：

amines; boranes; frustrated Lewis pairs; hydrogen; FREE CATALYTIC-HYDROGENATION; MOLECULAR-STRUCTURE; H-2; ACTIVATION; BORANE; REACTIVITY; IMINES; B(C6F5)(3); CARBENE; CRYSTAL; COMPLEX;

D O I：

10.1002/anie.201104999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Channeling the frustration: Frustrated Lewis pairs (FLPs) consisting of Ar F 2BH 1 with NEt 3 or DABCO can activate H 2 under mild conditions. Theoretical calculations suggest two distinct reaction pathways for these two FLPs. For the "more frustrated" Ar F 2BH/NEt 3, H 2 is activated in a stepwise manner; for the "less frustrated" Ar F 2BH/DABCO, H 2 is activated in a concerted fashion (see scheme). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12227 / 12231

页数：5

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