Polymer Supported Vanadium Complexes as Catalysts for the Oxidation of Alkenes in Water

被引：26

作者：

Hsiao, Ming-Chieh ^{[1
]}

Liu, Shiuh-Tzung ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

CATALYSIS LETTERS | 2010年 / 139卷 / 1-2期

关键词：

Oxidation of olefins; Vanadium complex; Polyacrylate; Cross-linked polymer; Bishydroxylation; Epoxidation; CIS-DIHYDROXYLATION; ADIPIC ACID; CLEAVAGE; CYCLOHEXENE; EPOXIDATION; BONDS; H2O2;

D O I：

10.1007/s10562-010-0410-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polymer supported vanadium complexes (denoted as c-PMA (n) -V) were prepared by the complexation of vanadium ions onto a cross linked polyacrylate. c PMA (n) -V can catalyze the oxidative cleavage of olefins with a large excess of t-butyl hydroperoxide (TBHP) or bishydroxylation of olefins with 4 eq. of TBHP.

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页码：61 / 66

页数：6

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