Layer-by-layer surface freezing of linear alcohols at the graphite/liquid interface

被引：24

作者：

Messé, L

Perdigon, A

Clarke, SM

Castro, MA

Inaba, A

机构：

[1] Univ Cambridge, BP Inst, Cambridge CB3 0HE, England

[2] Univ Cambridge, Dept Chem, Cambridge CB3 0HE, England

[3] Inst Ciencia Mat Sevilla, Seville 41092, Spain

[4] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 560, Japan

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2003年 / 266卷 / 01期

关键词：

D O I：

10.1016/S0021-9797(03)00544-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Differential scanning calorimetry (DSC), incoherent elastic neutron scattering, and neutron diffraction are used to demonstrate the presence of adsorbed solid multilayers of linear alcohols at the graphite-liquid alcohol interface. All alcohols studied (C-5-C-18) are found to form at least one monolayer. In addition all the even alcohols investigated (C6OH to C18OH) show multilayer formation. However, only the short odd alcohols (C5OH to C11OH) clearly exhibit additional features indicating multilayer formation. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：19 / 27

页数：9

共 28 条

[1] The crystalline structures of the even alkanes hexane, octane, decane, dodecane and tetradecane monolayers adsorbed on graphite at submonolayer coverages and from the liquid [J].