Rapid, highly efficient and stereoselective deoxygenation of epoxides by ZrCl4/NaI

被引：34

作者：

Firouzabadi, H ^{[1
]}

Iranpoor, N ^{[1
]}

Jafarpour, M ^{[1
]}

机构：

[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 23期

关键词：

zirconium tetrachloride; sodium iodide; epoxide; deoxygenation;

D O I：

10.1016/j.tetlet.2005.04.005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An effective and highly chemoselective method is described for the rapid deoxygenation of different epoxides to the corresponding olefins using ZrCl4/NaI in anhydrous CH3CN, in excellent yields and with retention of relative stereochemistry. (c) 2005 Published by Elsevier Ltd.

引用

页码：4107 / 4110

页数：4

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