Rapid, highly efficient and stereoselective deoxygenation of epoxides by ZrCl4/NaI

被引：34

作者：

Firouzabadi, H ^{[1
]}

Iranpoor, N ^{[1
]}

Jafarpour, M ^{[1
]}

机构：

[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 23期

关键词：

zirconium tetrachloride; sodium iodide; epoxide; deoxygenation;

D O I：

10.1016/j.tetlet.2005.04.005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An effective and highly chemoselective method is described for the rapid deoxygenation of different epoxides to the corresponding olefins using ZrCl4/NaI in anhydrous CH3CN, in excellent yields and with retention of relative stereochemistry. (c) 2005 Published by Elsevier Ltd.

引用

页码：4107 / 4110

页数：4

共 52 条

[51] SYNTHESIS AND STRUCTURE OF MODERATELY STABLE METALLAOXETANES - (ETA-5-C5ME5)2(CH3)TAOCHRCH2 (R = H, C6H5) - INVESTIGATIONS OF THEIR DECOMPOSITION TO OLEFIN AND (ETA-5-C5ME5)2TA(=O)CH3 AND EVIDENCE REVEALING THAT THEY ARE NOT INTERMEDIATES IN THE DEOXYGENATION OF EPOXIDES BY [(ETA-5-C5ME5)2TA(CH3)] [J].

WHINNERY, LL ;

HENLING, LM ;

BERCAW, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) :7575-7582

[52] CONVENIENT METHODS FOR DEOXYGENATION OF EPOXIDES TO OLEFINS [J].

YAMADA, K ;

GOTO, S ;

NAGASE, H ;

KYOTANI, Y ;

HIRATA, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (10) :2076-2077

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