Synthesis and structure of a stable cyclic dialkylgermylene

被引：63

作者：

Kira, M ^{[1
]}

Ishida, S ^{[1
]}

Iwamoto, T ^{[1
]}

Ichinohe, M ^{[1
]}

Kabuto, C ^{[1
]}

Ignatovich, L ^{[1
]}

Sakurai, H ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 03期

关键词：

D O I：

10.1246/cl.1999.263

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stable cyclic dialkylgermylene(1) was synthesized by reductive dechlorination of the corresponding dichlorogermane (6) with sodium. Germylene 1 is monomeric both in solution and in the solid state, as observed by UV-vis spectroscopy and X-ray crystallography.

引用

页码：263 / 264

页数：2

共 40 条

[11] BIVALENT GERMANIUM, TIN, AND LEAD 2,6-DI-TERT-BUTYLPHENOXIDES AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF M(OC6H2ME-4-BUT2-2,6)2 (M=GE OR SN) [J].

CETINKAYA, B ;

GUMRUKCU, I ;

LAPPERT, MF ;

ATWOOD, JL ;

ROGERS, RD ;

ZAWOROTKO, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (06) :2088-2089

[12] SUBVALENT GROUP-14 METAL-COMPOUNDS .14. THE X-RAY CRYSTAL-STRUCTURES OF 2 MONOMERIC GROUP-14 METAL BISAMIDES, GE[N(SIME3)2]2 AND SN[NC(ME)2(CH2)3CME2]2 [J].

CHORLEY, RW ;

HITCHCOCK, PB ;

LAPPERT, MF ;

LEUNG, WP ;

POWER, PP ;

OLMSTEAD, MM .

INORGANICA CHIMICA ACTA, 1992, 198 :203-209

[13] SUB-VALENT GROUP 4B METAL ALKYLS AND AMIDES .1. SYNTHESIS AND PHYSICAL-PROPERTIES OF KINETICALLY STABLE BIS[BIS(TRIMETHYSILYL)METHYL]-GERMANIUM(II), BIS[BIS(TRIMETHYSILYL)METHYL]-TIN(II), AND BIS[BIS(TRIMETHSILYL)METHYL]-LEAD(II) [J].

DAVIDSON, PJ ;

HARRIS, DH ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21) :2268-2274

[14] Germanium-containing heterobicyclic 10-pi-electron ring systems. Synthesis and characterization of neutral and cationic germanium(II) derivatives of aminotroponiminates [J].

Dias, HVR ;

Wang, ZY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (20) :4650-4655

[15] DIPHOSPHANYL-SUBSTITUTED AND DIARSANYL-SUBSTITUTED CARBENE HOMOLOGS - GERMANEDIYLS, STANNANEDIYLS, AND PLUMBANEDIYLS WITH REMARKABLE ELECTRONIC-STRUCTURES [J].

DRIESS, M ;

JANOSCHEK, R ;

PRITZKOW, H ;

RELL, S ;

WINKLER, U .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (15) :1614-1616

[16]

Driess M, 1996, ANGEW CHEM INT EDIT, V35, P829

[17] CHEMISTRY OF BULKY ALKOXIDES OF BIVALENT GERMANIUM AND TIN - STRUCTURES OF GASEOUS [SN(OBUT)2]2 AND CRYSTALLINE GE(OCBUT3)2 [J].

FJELDBERG, T ;

HITCHCOCK, PB ;

LAPPERT, MF ;

SMITH, SJ ;

THORNE, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (14) :939-941

[18] SUBVALENT GROUP-4B METAL ALKYLS AND AMIDES .5. SYNTHESIS AND PHYSICAL-PROPERTIES OF THERMALLY STABLE AMIDES OF GERMANIUM(II), TIN(II), AND LEAD(II) [J].

GYNANE, MJS ;

HARRIS, DH ;

LAPPERT, MF ;

POWER, PP ;

RIVIERE, P ;

RIVIEREBAUDET, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (20) :2004-2009

[19] CYCLIC METAL AMIDES .2. STABLE CYCLIC GERMANEDIYLS (CYCLOGERMYLENES) - SYNTHESIS, STRUCTURE, METAL-COMPLEXES, AND THERMOLYSES [J].

HERRMANN, WA ;

DENK, M ;

BEHM, J ;

SCHERER, W ;

KLINGAN, FR ;

BOCK, H ;

SOLOUKI, B ;

WAGNER, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (11) :1485-1488

[20] METAL (LI, GE-II, GE-III, SN-II, AND PB-II) 2,6-DIALKYLBENZENETHIOLATES - X-RAY CRYSTAL-STRUCTURES OF SN(SAR)2 (AR = C6H2BUT3-2,4,6) AND [M(SAR')2]3 (M = SN OR PB, AR' = C6H3PRI2-2,6) [J].

HITCHCOCK, PB ;

LAPPERT, MF ;

SAMWAYS, BJ ;

WEINBERG, EL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (24) :1492-1494

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