What have we learned about topochemical diacetylene polymerizations?

被引:30
作者
Curtis, SM [1 ]
Le, N [1 ]
Nguyen, T [1 ]
Xi, OY [1 ]
Tran, T [1 ]
Fowler, FW [1 ]
Lauher, JW [1 ]
机构
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
关键词
polydiacetylenes; topochemical polymerizations; crystal design; host-guest chemistry; hydrogen bonding;
D O I
10.1080/10610270412331328916
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of five polydiacetylenes have been synthesized via topochemical polymerizations of the corresponding monomers. The requisite structural parameters for the polymerization were achieved by the use of a host-guest co-crystal strategy. The atom trajectories of the polymerization reactions are discussed.
引用
收藏
页码:31 / 36
页数:6
相关论文
共 12 条
  • [1] SOLID-STATE SYNTHESIS OF LARGE POLYMER SINGLE-CRYSTALS
    BAUGHMAN, RH
    [J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1974, 12 (08) : 1511 - 1535
  • [2] Molecular symmetry and the design of molecular solids: The oxalamide functionality as a persistent hydrogen bonding unit
    Coe, S
    Kane, JJ
    Nguyen, TL
    Toledo, LM
    Wininger, E
    Fowler, FW
    Lauher, JW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (01) : 86 - 93
  • [3] Fowler FW, 2000, J PHYS ORG CHEM, V13, P850, DOI 10.1002/1099-1395(200012)13:12<850::AID-POC316>3.0.CO
  • [4] 2-L
  • [5] The topochemical 1,16-polymerization of a triene
    Hoang, T
    Lauher, JW
    Fowler, FW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (36) : 10656 - 10657
  • [6] PREPARATION OF LAYERED DIACETYLENES AS A DEMONSTRATION OF STRATEGIES FOR SUPRAMOLECULAR SYNTHESIS
    KANE, JJ
    LIAO, RF
    LAUHER, JW
    FOWLER, FW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (48) : 12003 - 12004
  • [7] Commensurate and incommensurate hydrogen bonds. An exercise in crystal engineering
    Nguyen, TL
    Fowler, FW
    Lauher, JW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (44) : 11057 - 11064
  • [8] SCHMIDT G M J, 1971, Pure and Applied Chemistry, V27, P647
  • [9] WEGNER G, 1969, Z NATURFORSCH PT B, VB 24, P824
  • [10] Single-crystal-to-single-crystal topochemical polymerizations of a terminal diacetylene: Two remarkable transformations give the same conjugated polymer
    Xi, OY
    Fowler, FW
    Lauher, JW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (41) : 12400 - 12401