Highly Selective CO2 Capture by a Flexible Microporous Metal-Organic Framework (MMOF) Material

被引：161

作者：

Wu, Haohan ^{[1
]}

Reali, Randall S. ^{[2
]}

Smith, David A. ^{[2
]}

Trachtenberg, Michael C. ^{[2
]}

Li, Jing ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

[2] Carbozyme Inc, Monmouth Jct, NJ 08852 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 47期

关键词：

adsorption; carbon dioxide; carbon dioxide fixation; metal-organic frameworks; microporous materials; separation selectivity; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE; COORDINATION-POLYMER; HIGH-CAPACITY; SEPARATION; ADSORPTION; MIL-53; CH4; MEMBRANES; GASES;

D O I：

10.1002/chem.201002683

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Caught in a CO2 trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N2, H 2, CH4, CO, and O2, with separation ratios of 294, 190, 257, and 441 for CO2/N2, CO2/H 2, CO2/CH4, and CO2/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO2/O 2 at 0.2 atm and 25 °C. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13951 / 13954

页数：4

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