Synthesis of Terpolymers by Click Reactions

被引:65
作者
Altintas, Ozcan [2 ]
Tunca, Umit [1 ]
机构
[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
[2] Karlsruhe Inst Technol, Inst Polymer Chem, D-76128 Karlsruhe, Germany
关键词
catalysis; copper; cycloaddition; radicals; terpolymers; RING-OPENING POLYMERIZATION; MIKTOARM STAR TERPOLYMERS; ONE-POT SYNTHESIS; AZIDE-ALKYNE CYCLOADDITION; H-SHAPED TERPOLYMERS; DIELS-ALDER REACTION; RADICAL POLYMERIZATION; BLOCK-COPOLYMERS; THERMO-RESPONSIBILITY; TRIBLOCK TERPOLYMERS;
D O I
10.1002/asia.201100138
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Well-defined polymeric structures were easily generated through living polymerization systems, in particular, living radical polymerizations. The polymeric precursors with orthogonal functionalities were subsequently clicked together with single or double (combinatorial) click reactions, such as the copper-catalyzed azide-cycloadditions (CuAAC) and Diels-Alder reactions, to create a wide variety of linear and nonlinear terpolymers.
引用
收藏
页码:2584 / 2591
页数:8
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